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  • Online Resource  (4)
  • 1965-1969  (4)
  • 1955-1959
  • 1968  (4)
  • Humanities.
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  • Online Resource  (4)
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  • 1965-1969  (4)
  • 1955-1959
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  • 1
    Online Resource
    Online Resource
    Dordrecht : Springer Netherlands
    ISBN: 9789401168939
    Language: English
    Pages: Online-Ressource (XIII, 376 p) , online resource
    Edition: Springer eBook Collection. Humanities, Social Sciences and Law
    Parallel Title: Erscheint auch als
    Parallel Title: Erscheint auch als
    Parallel Title: Erscheint auch als
    Keywords: Science (General) ; Social sciences. ; Humanities.
    Abstract: to Volume Two -- Classification -- The 18-electron rule -- 1. Two-Electron Ligands -- A. Classification -- B. The preparation of olefin-transition metal complexes -- C. A molecular orbital description of the bonding in organo-metallic complexes -- D. A description of the bonding of 2-electron ligands to transition metals -- E. General comments of 2-electron ligands -- F. Particular complexes of metals with 2-electron ligands -- 2. Three-Electron Ligands -- A. Preparation of ?-enyl complexes -- B. The structure of ?-enyl complexes -- C. The ?-allyl metal bond -- D. Dynamic equilibria in allyl complexes -- E. The chemistry of particular ?-enyl complexes -- 3. Four-Electron Ligands -- A. Some differences between unconjugated and conjugated olefin ligands -- B. The bonding of 4-electron ligands to transition metals -- C. Particular studies -- 4. Five-Electron Ligands -- A. Cyclopentadienyl metal complexes -- B. ?-Cyclopentadienyl transition metal complexes -- C. Cyclopentadienide transition metal complexes -- D. The bonding in mono-?-cyclopentadienyl transition metal complexes -- E. ?-Cyclopentadienyl carbonyl complexes -- F. ?-Cyclopentadienyl nitrosyl complexes -- G. Brief notes on binuclear ?-cyclopentadienyl complexes containing bridging ligands -- H. ?-Cyclopentadienyl hydride complexes -- I. ?-Cyclopentadienyl halides and oxides -- J. Other 5-electron ligands -- K. The organic chemistry of ?-cyclopentadienyl transition metal complexes -- L. Some particular reactions -- 5. Six-Electron Ligands -- A. Arene transition metal complexes -- (a) Preparation -- B. Olefin 6-electron ligands -- C. Transition metal complexes containing ?-bonded heterocyclic ligands -- 6. Seven-Electron Ligands Mixed Sandwich Complexes Related Azulene Derivatives and Cyclo-Octatetraene Complexes -- A. 7-Electron ligands -- B. Mixed sandwich complexes -- C. Metal complexes formed from azulenes -- D. Cyclo-octatetraene complexes -- 7. One-Electron Ligands -- I.1. Hydrocarbon alkyl and aryl complexes -- I.2 Transition metal-acyl complexes -- I.3. ?-Cyclopentadienyl complexes -- II. Transition metal fluorocarbon complexes -- III. Transition metal acetytides and alkynyls -- 8. Organometallic Complexes Formed From Acetylenes -- A. Monoacetylene, mononuclear complexes: acetylenes as 2-elec-tron ligands -- B. Monoacetylene binuclear complexes: acetylenes as 4-electron ligands -- C. Monoacetylene trinuclear complexes -- D. Monoacetylene tetranuclear complexes -- E. Bis-acetylene mononuclear complexes -- F. Bis-acetylene trinuclear complexes -- G. Tris-acetylene mononuclear complexes -- H. Tris-acetylene binuclear complexes -- I. Miscellaneous -- 9. The Role of Organotransition Metal Complexes in Some Catalytic Reactions -- A. Some chemistry of transition metal hydride complexes -- B. Some catalytic reactions which involve hydrogen transfer: isomerization reactions -- C. Homogeneous hydrogenation of olefins and acetylenes -- D. Some dimerization oligomerization and polymerization reactions of olefins and acetylenes -- E. Hydroformylation and related carhonylation reactions -- F. Some general comments on the relationship between heterogeneous and homogeneous transition metal catalysts -- G. Miscellaneous -- Author -- Subject -- Crystal Structures〉.
    Abstract: to thank Messrs J. R. Sanders, W. E. Lindsell and M. G. Swanwick for helping to check the text and references and prepare indexes. Finally, I should like to thank my wife for the very considerable assis­ tance she has given me in the writing and production of this book. M. L. H. G. Contents Preface to the Third Edition, Volume Two Page v INTRODUCTION TO VOLUME TWO I Oassification I The IS-electron rule 2 (i) The basis of the I8-electron rule p. 4, (ii) Exceptions to the I8-electron rule p. 5 1. TWO-ELECTRON LIGANDS 7 A. Classification 7 B. The preparation of olefin-transition metal complexes 7 (a) Displacement of solvent ligands p. 9, (b) Preparations from metal carbonyls p. 9, (c) Less common preparative routes p. 11, Reductive olefination method p. 12 C. A molecular orbital description of the bonding in orga- metallic complexes 13 (a) General comments p. 13, (b) Symmetry considerations p. 13, (c) Energies of the molecular orbitals p. 14 D. A description of the bonding of 2-electron ligands to transition metals 14 E. General comments of 2-electron ligands 19 (a) Infrared studies p. 20, (b) Effect of olefin substituents p. 21, (c) The rotation of ethylene about the ligand-metal bond p. 22, (d) Chemical properties p. 23 F. Particular complexes of metals with 2-electron ligands 25 (a) Copper, silver and gold p. 25, Complexes with benzene p. 28, (b) Nickel, palladium and platinum p.
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  • 2
    Online Resource
    Online Resource
    Boston, MA : Springer US
    ISBN: 9781468464597
    Language: English
    Pages: Online-Ressource (XV, 484 p) , online resource
    Edition: Springer eBook Collection. Humanities, Social Sciences and Law
    Parallel Title: Erscheint auch als
    Parallel Title: Erscheint auch als
    Parallel Title: Erscheint auch als
    Parallel Title: Erscheint auch als
    Keywords: Science (General) ; Social sciences. ; Humanities.
    Abstract: 1. Purpose of Protective Relays and Relaying. Causes of Faults. Definitions. Functions of Protective Relays. Application to a Power System -- 2. Relay Design and Construction. Characteristics. Choice of Measuring Units. Construction of Measuring Units. Construction of Timing Units. Details of Design. Cases. Panel Mounting. Operation Indicators. Finishes -- 3. The Main Characteristics of Protective Relays. Phase and Amplitude Comparators. Relay Characteristics. General Equation for Characteristics. Inversion Chart. Resonance. Appendix -- 4. Overcurrent Protection. Time-Current Characteristics. Application. Limits of Error. Ratings. Directional Overcurrent Protection. A.C. Tripping. Schemes for Radial Feeders. Construction. Application. Problem -- 5. Distance Relays. General Principles. Special Characteristics. Limitations. Application to Lines. Settings. Multi-terminal Lines. Construction. A.C. Potential Supply. Simultaneous Ground Faults. Auto-reclosing Zero Sequence Compensation -- 6. Switched and Polyphase Distance Relays. Reduction of Measuring Units. Automatic Switching Schemes. Polyphase Distance Relays. Phase and Amplitude Comparators. Analysis of Polyphase Comparators -- 7. Directional Pilot Relaying. Basic Principles. Pilot Wire Schemes. Carrier Channel Schemes. Carrier Signal Checking. Future Trends -- 8. A.C. Pilot Relaying. Pilot Wire Schemes. Phase and Amplitude Comparators. Effect of Load Current. Multi-terminal Lines. Pilot Wire Limitations. Pilot Supervision. Phase Comparison Carrier -- 9. Protection of A.C. Machines. Generator Protection. Stator Faults. Rotor Faults. Miscellaneous Faults. Motor Protection. Faults. Unbalanced Conditions. Power Station Auxiliaries. Current Differential Relaying -- 10. Power Transformer Protection. Types of Faults. Gas Relays. Differential Relays. Magnetising Inrush. Minimising of Effects. Relay Solutions. Grounding Transformers. Generator Transformer Units. Transformer Feeders -- 11. Bus-Zone Protection. General Principles. Current Differential Protection. Voltage Differential. Frame Leakage Protection. Directional Comparison. Back-up. Supervision -- 12. Back-Up Protection. Basic Principles. Precautions for Reliability Remote Back-up. Local Back-up. Relay Back-up. Breaker Back-up. A.C. Supplies. D.C. Supply -- 13. Maintenance and Testing of Relays. Commissioning. Periodic Maintenance. Transfer to Test Circuit. Tools. Safety Measures. Mechanical Tests. Electrical Tests. Manufacture Tests -- 14. Miscellaneous. Static Relays. Future of Electromagnetic Relays. D.C. Protection Relays. Protection Engineering as a Career -- References.
    Description / Table of Contents: 1. Purpose of Protective Relays and Relaying. Causes of Faults. Definitions. Functions of Protective Relays. Application to a Power System2. Relay Design and Construction. Characteristics. Choice of Measuring Units. Construction of Measuring Units. Construction of Timing Units. Details of Design. Cases. Panel Mounting. Operation Indicators. Finishes -- 3. The Main Characteristics of Protective Relays. Phase and Amplitude Comparators. Relay Characteristics. General Equation for Characteristics. Inversion Chart. Resonance. Appendix -- 4. Overcurrent Protection. Time-Current Characteristics. Application. Limits of Error. Ratings. Directional Overcurrent Protection. A.C. Tripping. Schemes for Radial Feeders. Construction. Application. Problem -- 5. Distance Relays. General Principles. Special Characteristics. Limitations. Application to Lines. Settings. Multi-terminal Lines. Construction. A.C. Potential Supply. Simultaneous Ground Faults. Auto-reclosing Zero Sequence Compensation -- 6. Switched and Polyphase Distance Relays. Reduction of Measuring Units. Automatic Switching Schemes. Polyphase Distance Relays. Phase and Amplitude Comparators. Analysis of Polyphase Comparators -- 7. Directional Pilot Relaying. Basic Principles. Pilot Wire Schemes. Carrier Channel Schemes. Carrier Signal Checking. Future Trends -- 8. A.C. Pilot Relaying. Pilot Wire Schemes. Phase and Amplitude Comparators. Effect of Load Current. Multi-terminal Lines. Pilot Wire Limitations. Pilot Supervision. Phase Comparison Carrier -- 9. Protection of A.C. Machines. Generator Protection. Stator Faults. Rotor Faults. Miscellaneous Faults. Motor Protection. Faults. Unbalanced Conditions. Power Station Auxiliaries. Current Differential Relaying -- 10. Power Transformer Protection. Types of Faults. Gas Relays. Differential Relays. Magnetising Inrush. Minimising of Effects. Relay Solutions. Grounding Transformers. Generator Transformer Units. Transformer Feeders -- 11. Bus-Zone Protection. General Principles. Current Differential Protection. Voltage Differential. Frame Leakage Protection. Directional Comparison. Back-up. Supervision -- 12. Back-Up Protection. Basic Principles. Precautions for Reliability Remote Back-up. Local Back-up. Relay Back-up. Breaker Back-up. A.C. Supplies. D.C. Supply -- 13. Maintenance and Testing of Relays. Commissioning. Periodic Maintenance. Transfer to Test Circuit. Tools. Safety Measures. Mechanical Tests. Electrical Tests. Manufacture Tests -- 14. Miscellaneous. Static Relays. Future of Electromagnetic Relays. D.C. Protection Relays. Protection Engineering as a Career -- References.
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  • 3
    ISBN: 9781468471618
    Language: English
    Pages: Online-Ressource , online resource
    Edition: Springer eBook Collection. Humanities, Social Sciences and Law
    Parallel Title: Erscheint auch als
    Parallel Title: Erscheint auch als
    Parallel Title: Erscheint auch als
    Keywords: Science (General) ; Social sciences. ; Humanities.
    Abstract: 1 Introduction -- 2 Genesis of the Hymenoptera -- Palaeontological and comparative morphological data. Hypotheses on the origin of the Hymenoptera -- The archaic terrestrial phase -- 3 Genesis of the Lower Hymenoptera (Phytophaga) -- The transition from saprophytic feeding to phytophagy. The exophytic cephoid phase. Modern relicts -- The endophytic cephoid phase. The transition from feeding on normal plant tissues to feeding on galls -- 4 Genesis of the Terebrantia -- The problem of the origin of the first carnivorous Hymenoptera -- Hypotheses on the origin of the Terebrantia -- The transition from phytophagy to zoophagy and the genesis of the Terebrantia -- The archaic inquilinoid phase -- The predatory oöphagous (ectoöphagous) phase -- The parasitic oöphagous (endoöphagous) phase -- The secondary phytophagous (phytoöphagous) phase -- The delayed parasitic (metaparasitic) phase -- The intermediate parasitic (planidial) phase -- The hypermetamorphic parasitic phase -- The polyembryonic parasitic phase -- The passive parasitic (trigonaloid) phase -- The direct parasitic (orthoparasitic) phase -- The imaginai parasitic phase -- 5 Genesis of the Wasps (Vespiformia s. lat.) -- The problem of the origin of the wasps -- Elements of wasp life in the Terebrantia -- The wasp-like (bethyloid) phase page -- The primary wasp (pompiloid) phase -- The secondary wasp (sphecoid) phase -- The third wasp (crabronoid) phase -- The fourth wasp (bembicoid) phase -- The fifth wasp (moneduloid) phase -- The neo-wasp (vespoid) phase -- The hypotheses of Bouvier and his followers on the origin of the instincts of wasps -- 6 Genesis of the Ants (Formicoidea) -- Hypotheses on the origin of the ants. The problem -- The predatory semi-familial phase -- The ectoparasitic semi-familial phase -- The familial ectoparasitic (hemiformicoid) phase -- The primary ant (proformicoid) phase -- The secondary ant (formicoid) phase -- 7 Genesis of the Bees (Apoidea) -- Hypotheses on the origin of the bees. The problem -- The bee-like phase in the vespoid wasps -- The primary bee phase of vespoid type -- The secondary bee phase of vespoid type -- Evolution of the sphecoid wasps and the problem of the genesis of the true bees -- The primary bee phase of sphecoid type and its genesis -- Index of Authors -- Index of Latin Names.
    Abstract: The late Professor S. I. Malyshev, who died from a cerebral haemorrhage on 9 May 1967 at the age of 83 in the train while travelling to field work, was one of the foremost European students of the Hymenoptera, in particular of the habits of solitary bees, a subject on which he had published many papers since 1908, mostly in Russian. In 1935 he published an important paper on part of his work, and I helped to edit the publication, which was in English. A few years ago some of my friends in California asked me if I could not persuade him to complete his early paper on solitary bees, offering if necessary to arrange for a translation. When I wrote to Professor Malyshev making this suggestion he no longer had the health to produce a new work, but he sent me a copy of his recent book on the evolution of the Hymenoptera which he thought might be worth trans­ lating. Sir Boris Uvarov was good enough to translate for me the chapter and section headings, and it seemed to both of us that a lot of new ground was covered in a highly original way. The explanation of the changes in behaviour that must have taken place when the simple, plant-feeding saw­ flies developed into highly specialized parasites or into industrious, food­ collecting, social insects such as the ants, bees, and wasps can well be regarded as one of the major challenges to zoologists.
    Description / Table of Contents: 1 Introduction2 Genesis of the Hymenoptera -- Palaeontological and comparative morphological data. Hypotheses on the origin of the Hymenoptera -- The archaic terrestrial phase -- 3 Genesis of the Lower Hymenoptera (Phytophaga) -- The transition from saprophytic feeding to phytophagy. The exophytic cephoid phase. Modern relicts -- The endophytic cephoid phase. The transition from feeding on normal plant tissues to feeding on galls -- 4 Genesis of the Terebrantia -- The problem of the origin of the first carnivorous Hymenoptera -- Hypotheses on the origin of the Terebrantia -- The transition from phytophagy to zoophagy and the genesis of the Terebrantia -- The archaic inquilinoid phase -- The predatory oöphagous (ectoöphagous) phase -- The parasitic oöphagous (endoöphagous) phase -- The secondary phytophagous (phytoöphagous) phase -- The delayed parasitic (metaparasitic) phase -- The intermediate parasitic (planidial) phase -- The hypermetamorphic parasitic phase -- The polyembryonic parasitic phase -- The passive parasitic (trigonaloid) phase -- The direct parasitic (orthoparasitic) phase -- The imaginai parasitic phase -- 5 Genesis of the Wasps (Vespiformia s. lat.) -- The problem of the origin of the wasps -- Elements of wasp life in the Terebrantia -- The wasp-like (bethyloid) phase page -- The primary wasp (pompiloid) phase -- The secondary wasp (sphecoid) phase -- The third wasp (crabronoid) phase -- The fourth wasp (bembicoid) phase -- The fifth wasp (moneduloid) phase -- The neo-wasp (vespoid) phase -- The hypotheses of Bouvier and his followers on the origin of the instincts of wasps -- 6 Genesis of the Ants (Formicoidea) -- Hypotheses on the origin of the ants. The problem -- The predatory semi-familial phase -- The ectoparasitic semi-familial phase -- The familial ectoparasitic (hemiformicoid) phase -- The primary ant (proformicoid) phase -- The secondary ant (formicoid) phase -- 7 Genesis of the Bees (Apoidea) -- Hypotheses on the origin of the bees. The problem -- The bee-like phase in the vespoid wasps -- The primary bee phase of vespoid type -- The secondary bee phase of vespoid type -- Evolution of the sphecoid wasps and the problem of the genesis of the true bees -- The primary bee phase of sphecoid type and its genesis -- Index of Authors -- Index of Latin Names.
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  • 4
    Online Resource
    Online Resource
    Berlin : Springer
    ISBN: 9783642874246
    Language: English
    Pages: Online-Ressource , digital
    Edition: Springer eBook Collection. Humanities, Social Sciences and Law
    Series Statement: Springer Tracts in Natural Philosophy 16
    Parallel Title: Erscheint auch als
    Parallel Title: Erscheint auch als
    Parallel Title: Erscheint auch als
    Keywords: Science (General) ; Social sciences. ; Humanities.
    Abstract: 1. Connected Networks -- 1.0 Introduction -- 1.1 Set Theory -- 1.2 Sets with Two or Less Elements -- 1.3 Generalized Union -- 1.4 Relations and Functions -- 1.5 Superpositions and Inverses -- 1.6 Restrictions -- 1.7 Cartesian Products -- 1.8 Some Special Symbols -- 1.9 Finite Sequences -- 1.10 Networks -- 1.11 Geometrical Realization of a Network -- 1.12 Subnetworks -- 1.13 Degree of a Vertex -- 1.14 Path in a Network -- 1.15 Proper Path in a Network -- 1.16 Reduction of a Path to a Proper Path -- 1.17 Connected Networks -- 1.18 Isolated Vertices -- 1.19 Connected Sets of Branches -- 1.20 Path Connected Set of Branches -- 1.21 Union of Connected Sets of Branches -- 1.22 Connectedness of Paths -- 1.23 Component of a Set of Branches -- 1.24 Existence of Components -- 1.25 Partition into Components -- 1.26 Removal of a Branch -- 2. Loops, Trees, and Cut Sets -- 2.0 Introduction -- 2.1 Loop in a Network -- 2.2 Loops -- 2.3 Subloops of a Loop -- 2.4 Branches and Vertices of a Loop -- 2.5 Paths in a Loop -- 2.6 Removal of a Branch from a Loop -- 2.7 Tree in a Network -- 2.8 Trees -- 2.9 Connected Subset of a Tree -- 2.10 Branches and Vertices of a Tree -- 2.11 Number of Vertices of a Connected Set of Branches -- 2.12 Addition of a Branch to a Tree -- 2.13 Existence of Maximal Trees -- 2.14 Cut Set in a Network -- 2.15 Existence of Cut Sets -- 2.16 Alternate Characterization of Cut Sets -- 3. Incidence Functions and Incidence Matrices -- 3.0 Introduction -- 3.1 Incidence Functions -- 3.2 Matrices and Arrays -- 3.3 Submatrices -- 3.4 Determinants -- 3.5 Incidence Matrices -- 3.6 Square Submatrices of an Incidence Matrix -- 3.7 Unimodular Matrices -- 3.8 Laplacian Expansion of a Determinant -- 3.9 Reduced Incidence Matrix of a Tree -- 3.10 Incidence Matrix of a Loop -- 4. Linear Algebra Review -- 4.0 Introduction -- 4.1 The Field of Scalars -- 4.2 Addition and Scalar Multiplication of Functions -- 4.3 Linear Space of 0-Chains -- 4.4 Canonical Base of the Space of 0-Chains -- 4.5 Inner Product -- 4.6 Linear Maps -- 4.7 Transpose of a Linear Map -- 4.8 Direct Sum Decomposition -- 4.9 Dimension and Direct Sum Decomposition -- 5. Boundary Operator and Coboundary Operator -- 5.0 Introduction -- 5.1 Assumptions of This Chapter -- 5.2 Chain Spaces -- 5.3 The Boundary Operator -- 5.4 Boundaries and Cycles -- 5.5 Summation Over Finite Sets -- 5.6 The Coboundary Operator -- 5.7 Coboundaries and Cocycles -- 5.8 Boundaries, Coboundaries, and Inner Products -- 5.9 Orthogonality of Cycles and Coboundaries -- 5.10 Orthogonality of Boundaries and Cocycles -- 5.11 Decomposition of ?(K) into Cycles and Coboundaries -- 5.12 Decomposition of ? (V) into Boundaries and Cocycles -- 5.13 Isomorphism of Coboundaries and Boundaries -- 5.14 Dimension of the Space of Cocycles -- 6. Axioms of Network Analysis -- 6.0 Introduction -- 6.1 Assumptions of This Chapter -- 6.2 Resistive Networks -- 6.3 Currents and Voltages -- 6.4 Ohm’s Law -- 6.5 Sources -- 6.6 Kirchhoff’s Laws for Voltage Sources -- 6.7 Kirchhoff’s Laws for Current Sources -- 7. Existence and Uniqueness of Solutions -- 7.0 Introduction -- 7.1 Assumptions of This Chapter -- 7.2 Linearity of L and H -- 7.3 Existence and Uniqueness with Voltage Sourcess -- 7.4 Existence and Uniqueness with Current Sources -- 7.5 Current Variables -- 7.6 Voltage Variables -- 8. Kirchhoff’s Third and Fourth Laws -- 8.0 Introduction -- 8.1 Assumptions of This Chapter -- 8.2 The Cycle Map -- 8.3 The Chord Map -- 8.4 The Sum of Tree Chord Products -- 8.5 The Current Chain with Voltage Sources -- 8.6 The Coboundary Map -- 8.7 The Tree Branch Map -- 8.8 The Sum of Tree Branch Products -- 8.9 The Voltage Chain with Current Sources -- 8.10 Invariance Under Change of Incidence -- References.
    Abstract: In this book we attempt to develop the fundamental results of resistive network analysis, based upon a sound mathematical structure. The axioms upon which our development is based are Ohm's Law, Kirchhoff's Voltage Law, and Kirchhoff's Current Law. In order to state these axioms precisely, and use them in the development of our network analysis, an elaborate mathematical structure is introduced, involving concepts of graph theory, linear algebra, and one dimensional algebraic topology. The graph theory and one dimensional algebraic topology used are developed from first principles; the reader needs no background in these subjects. However, we do assume that the reader has some familiarity with elementary linear algebra. It is now stylish to teach elementary linear algebra at the sophomore college level, and we feel that the require­ ment that the reader should be familiar with elementary linear algebra is no more demanding than the usual requirement in most electrical engineering texts that the reader should be familiar with calculus. In this book, however, no calculus is needed. Although no formal training in circuit theory is needed for an understanding of the book, such experience would certainly help the reader by presenting him with familiar examples relevant to the mathematical abstractions introduced. It is our intention in this book to exhibit the effect of the topological properties of the network upon the branch voltages and branch currents, the objects of interest in network analysis.
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