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Telomerization of aceylonitkile and methyl acrylate with bromotrichloromethane in the presence of iron pentacarbonyl

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Initiating systems that contain iron pentacarbonyl and a cocatalyst (iodine, dimethylaniline) make it possible to run the telomerization of acrylonitrile and methyl acrylate with bromotrichloromethane under mild conditions, with a total yield of 55–65% of the first two telomer homologs.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    F. K. Velichko, L. V. Vinogradova & R. Kh. Freidlina

Authors
  1. F. K. Velichko
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  2. L. V. Vinogradova
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  3. R. Kh. Freidlina
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 181–184, January, 1973.

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Velichko, F.K., Vinogradova, L.V. & Freidlina, R.K. Telomerization of aceylonitkile and methyl acrylate with bromotrichloromethane in the presence of iron pentacarbonyl. Russ Chem Bull 22, 188–190 (1973). https://doi.org/10.1007/BF00854160

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  • DOI: https://doi.org/10.1007/BF00854160

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